Synthesis of a chloro protected iridium nitrido complex.

Syntheses and electronic structures of μ-nitrido bridged pyridine, diimine iridium complexes.

The syntheses and X-ray crystal structures of dinuclear μ-azido and μ-nitrido bridged iridium complexes bearing the pyridine, diimine ligand (PDI) are reported. Their electronic structures and formal oxidation states of the metal centers are analyzed by theoretical and experimental methods, revealing the non-innocence of the PDI and nitrido ligands.

Coupling of terminal iridium nitrido complexes†

Kinetic, mechanistic and thermodynamic investigations on Iridium (III) catalyzed oxidation of D-Mannitol by N-chloro-p-toluenesulfonamide in perchloric acid medium

The present paper deals with the kinetics and mechanism of homogeneously Ir(III) chloride catalyzed oxidation of D-mannitol by chloramine-T [CAT] in perchloric acid medium in the temperature range of 30 to 45 0C. The reaction is carried out in the presence of mercuric acetate as a scavenger for chloride ion. The experimental results show first order kinetics with respect to the oxidant [CAT] an...

Synthesis and Characterization of Aminocarboxylato Iridium(III) Complexes

Aminocarboxylic acids, such as 2-aminobenzoic acid, react easily with [Ir(COD)(PMe3)3]Cl, (COD=1,5-cyclooctadiene), in THF to produce hydridoaminocarboxylato iridium(III) complexes in high yields. These octahedral complexes are formed via oxidative addition reaction of the O-H bond of the carboxylic group with the central metal. The starting iridium(I) complex losses t...

;r-01efin-Iridium-Komplexe, XVIII [1] Reaktionen von Bis[cycloocta-l,5-dien-//-chloro-iridium] mit w-Propyllithium in Gegenwart von Alkinen yr-Olefin Iridium Complexes, XVIII [1] Reactions of Bis[cycloocta-l,5-diene-/z-chloro-iridium] with n -Propyllithium in the Presence of Alkynes

Herrn Prof. Dr. Dr. h. c. mult. E. O. Fischer zum 75. Geburtstag gewidm et Z. Naturforsch. 48 b, 1558-1564 (1993); eingegangen am 15. Juli 1993 Substituted Benzene, Cyclohexadienyl and Iridacyclopentadienyl Complexes, Synthesis, NMR Spectra, Crystal Structure The reaction of [(cod)IrCl]2 (cod = //4-cycloocta-l,5-diene) with n-C3H7Li gives non-isolable (cod)IrH species by /3-elimination of (cod)...